Being an accomplice is an interesting character hook. And not just for villainous exploits either. Imagine a game where the PCs are all sidekicks of major superheroes - a group of PCs playing Jimmy Olsen, Bucky Barnes, and Robin. The heroes go off and do something, leaving the sidekicks behind when some secondary crisis erupts. Or perhaps the major heroes even get into trouble which is over their heads, and the sidekicks have to come to the rescue.
Transcript
Imperial Officer: My Lord, Starkiller—
Darth Vader: Has landed.
Imperial Officer: Well, I can see I'm not needed around here...
Darth Vader: Take Princess and the Wookiee to my ship.
Imperial Officer: Yes, my Lord!
Lando: Look, whatever's between you and your daughter is your business. But what did Chewbacca do?
Darth Vader: He was an accomplice to Solo's elaborate schemes to defraud the Empire and support the Rebellion.
Darth Vader: Five times.
{beat on Lando}
Lando: This is still my city. I'll escort them.
Imperial Officer: Oh, come on! What am I? Chopped splanch?